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Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tri­bromo­phen­yl)diazen­yl]naphthalen-2-ol

Identifieur interne : 000030 ( Main/Exploration ); précédent : 000029; suivant : 000031

Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tri­bromo­phen­yl)diazen­yl]naphthalen-2-ol

Auteurs : Souheyla Chetioui [Algérie] ; Djamil-Azzeddine Rouag [Algérie] ; Jean-Pierre Djukic [France] ; Christian G. Bochet [Suisse] ; Rachid Touzani [Maroc] ; Corinne Bailly [France] ; Aurélien Crochet [Suisse] ; Katharina M. Fromm [Suisse]

Source :

RBID : PMC:4971848

Abstract

In the title copper(II) complex, the metal atom is coordinated by two N atoms and two O atoms from two bidentate (E)-1-[(2,4,6-tri­bromo­phen­yl)diazen­yl]naphthalen-2-ol ligands, forming a slightly distorted square-planar environment. In the isotypic nickel(II) and palladium(II) complexes, the metal atoms are located on centres of inversion, hence the metal coordination spheres have perfect square-planar geometries.


Url:
DOI: 10.1107/S205698901601080X
PubMed: 27536389
PubMed Central: 4971848


Affiliations:


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<p>In the title copper(II) complex, the metal atom is coordinated by two N atoms and two O atoms from two bidentate (
<italic>E</italic>
)-1-[(2,4,6-tri­bromo­phen­yl)diazen­yl]naphthalen-2-ol ligands, forming a slightly distorted square-planar environment. In the isotypic nickel(II) and palladium(II) complexes, the metal atoms are located on centres of inversion, hence the metal coordination spheres have perfect square-planar geometries.</p>
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